Abstract:
Hybrid metal oxide-polymer nanocomposites are promising material combination for cost efficient
solar cells. However, the power conversion efficiency (PCE) of these hybrid solar cells are limited due to
several reasons, including poor chemical compatibility of inorganic acceptor and organic donor. Our group
recently reported that hole mobility of the polymer can be increased up to two order of magnitude when
an oligothiophene dye is introduced at TiO2 / P3HT interface modifier. This work focuses on studying the
influence of dyes, including a 3-hexylthiophene derivative dye with a cyanoacrylic acid group ((E)-2-cyano-
3-(3′,3′′,3′′′-trihexyl-[2,2′:5′,2′′:5′′,2′′′-quaterthiophene]-5-yl) acrylicacid) (4T), on the photovoltaic (PV)
performance of TiO2 / P3HT solar cells. The insertion of dye at the interface improves the efficiency
regardless of the dye used. However, 4T dye significantly improved the efficiency by a factor of three when
compared to the corresponding TiO2/P3HT solar cells. This improvement is mainly due to increase in short
circuit current density, which is consistent with higher hole mobility value of the polymer reported in
TiO2/P3HT nanocomposite with 4T dye. Optical absorption data further reveals that 4T extends spectral
response of TiO2/P3HT nanocomposite which could also enhance the short circuit current density. The
reduced dark currents upon dye insertion ensure that the carrier recombination is controlled at the
interface and this in turn increased the open circuit voltage. Optimised TiO2/P3HT device with 4T dye
showed average efficiency of about 2.0 % under simulated irradiation of 100 mWcm-2 (1 sun) with AM 1.5
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