Abstract:
Hydrogen gas is greener and reliable energy source, which can contribute to fill the gap between
the energy demand and energy supply. Several photocatalyst materials, such as TiO2, ZnO, CdS, WS2,
mixed oxides, perovskites, dye and metal doped oxide materials have been used as phototcatalysts for
energy production, such as water splitting applications and environmental remediation. Development of
efficient non-toxic photocatalyst has opened a new avenue for several other applications, such as in
lithium ion batteries, solar cells, etc. The production of hydrogen through water splitting is a green route
for converting solar energy directly in to clean fuel. Recently, the transition metal chalcogenides have
intensively been focused on hydrogen production due to their stronger edge and the quantum
confinement effect. This work mainly focuses on synthesis of cobalt disulfide (CoS2) embedded TiO2
nanocomposites using hydrothermal approach; and, the hydrogen production efficiencies of pure CoS2,
pure TiO2, and different wt% of CoS2 in TiO2 were compared under UV irradiation. Nanocrystalline TiO2
having 10 wt% CoS2 exhibits higher hydrogen production of 2.5492 mmol/gcatalyst in comparison with the
pure CoS2 or TiO2 used in this study. The bare CoS2 material was found to be inactive due to its very low
bandgap energy of 2.5 eV; however, the enhanced activity of the CoS2 loaded nanocomposite may be due
to the heterojunction frame work that causes the effective electron-hole pair separation. In summary,
the metal dichalcogenide, CoS2, acts as an effective co-catalyst, whereas titania serves as active site by
effectively separating the photogenerated electron-hole pair. This study lays down a new approach to
develop transition metal dichalcogenide materials with significant bandgaps that can effectively harness
solar energy for hydrogen production.
